Posts belonging to Category Automobile

Clean Hydrogen Produced From Biomass

A team of scientists at the University of Cambridge has developed a way of using solar power to generate a fuel that is both sustainable and relatively cheap to produce. It’s using natural light to generate hydrogen from biomass. One of the challenges facing modern society is what it does with its waste products. As natural resources decline in abundance, using waste for energy is becoming more pressing for both governments and business. Biomass has been a source of heat and energy since the beginning of recorded history.  The planet’s oil reserves are derived from ancient biomass which has been subjected to high pressures and temperatures over millions of years. Lignocellulose is the main component of plant biomass and up to now its conversion into hydrogen has only been achieved through a gasification process which uses high temperatures to decompose it fully.

biomass can produce hydrogen

Lignocellulose is nature’s equivalent to armoured concrete. It consists of strong, highly crystalline cellulose fibres, that are interwoven with lignin and hemicellulose which act as a glue. This rigid structure has evolved to give plants and trees mechanical stability and protect them from degradation, and makes chemical utilisation of lignocellulose so challenging,” says  Dr Moritz Kuehnel, from the Department of Chemistry at the University of Cambridge and co-author of the research.

The new technology relies on a simple photocatalytic conversion process. Catalytic nanoparticles are added to alkaline water in which the biomass is suspended. This is then placed in front of a light in the lab which mimics solar light. The solution is ideal for absorbing this light and converting the biomass into gaseous hydrogen which can then be collected from the headspace. The hydrogen is free of fuel-cell inhibitors, such as carbon monoxide, which allows it to be used for power.

The findings have been  published in Nature Energy.


NanoCar Race

The NanoCar Race is an event in which molecular machines compete on a nano-sized racetrack. These “NanoCars” or molecule-cars can have real wheels, an actual chassis…and are propelled by the energy of electric pulses! Nothing is visible to the naked eye, however a unique microscope located in Toulouse (France) will make it possible to follow the race. A genuine scientific prowess and international human adventure, the race is a one-off event, and will be broadcast live on the web, as well as at the Quai des Savoirs, science center in Toulouse.


The NanoCar race takes place on a very small scale, that of molecules and atoms: the nano scale…as in nanometer! A nanometer is a billionth of a meter, or 0.000000001 meters or 10 -9 m. In short, it is 500,000 times thinner then a line drawn by a ball point pen; 30,000 times thinner than the width of a hair; 100 times smaller than a DNA molecule; 4 atoms of silicon lined up next to one another.

A very powerful microscope is necessary to observe molecules and atoms: the scanning tunneling microscope (STM) makes this possible, and it is also responsible for propelling the NanoCars. The scanning tunneling microscope was invented in 1981 by Gerd Binnig and Heinrich Rohrer, and earned them the Nobel Prize in Physics in 1986. The tunnel effect is a phenomenon in quantum mechanics: using a tip and an electric current, the microscope will use this phenomenon to determine the electric conductance between the tip and the surface, in other words the amount of current that is passing through.

nanocar in movement Screening provides an electronic map of the surface and of each atom or molecule placed on it.At the CNRS‘s Centre d’élaboration de matériaux et d’études structurales (CEMES) in Toulouse, it is the one of a kind STM microscope that makes the race possible: the equivalent of four scanning tunneling microscopes, this device is the only one able to simultaneously and independently map four sections of the track in real time, thanks to its four tungsten tips.


Clean Renewable Source Of Hydrogen Fuel For Electric Car

Rice University scientists have created an efficient, simple-to-manufacture oxygen-evolution catalyst that pairs well with semiconductors for solar water splitting, the conversion of solar energy to chemical energy in the form of hydrogen and oxygen.

anode RiceA photo shows an array of titanium dioxide nanorods with an even coating of an iron, manganese and phosphorus catalyst. The combination developed by scientists at Rice University and the University of Houston is a highly efficient photoanode for artificial photosynthesis. Click on the image for a larger version

The lab of Kenton Whitmire, a Rice professor of chemistry, teamed up with researchers at the University of Houston and discovered that growing a layer of an active catalyst directly on the surface of a light-absorbing nanorod array produced an artificial photosynthesis material that could split water at the full theoretical potential of the light-absorbing semiconductor with sunlight. An oxygen-evolution  catalyst splits water into hydrogen and oxygen. Finding a clean renewable source of hydrogen fuel is the focus of extensive research, but the technology has not yet been commercialized.

The Rice team came up with a way to combine three of the most abundant metalsiron, manganese and phosphorus — into a precursor that can be deposited directly onto any substrate without damaging it. To demonstrate the material, the lab placed the precursor into its custom chemical vapor deposition (CVD) furnace and used it to coat an array of light-absorbing, semiconducting titanium dioxide nanorods. The combined material, called a photoanode, showed excellent stability while reaching a current density of 10 milliamps per square centimeter, the researchers reported.

The results appear in two new studies. The first, on the creation of the films, appears in Chemistry: A European Journal. The second, which details the creation of photoanodes, appears in ACS Nano.


Hydrogen Electric Car: New Storage System

Lawrence Livermore scientists have collaborated with an interdisciplinary team of researchers, including colleagues from Sandia National Laboratories, to develop an efficient hydrogen storage system that could be a boon for hydrogen-powered vehicles.

hydrogen lithiumHydrogenation forms a mixture of lithium amide and hydride (light blue) as an outer shell around a lithium nitride particle (dark blue) nanoconfined in carbon

Hydrogen is an excellent energy carrier, but the development of lightweight solid-state materials for compact, low-pressure storage is a huge challenge. Complex metal hydrides are a promising class of hydrogen storage materials, but their viability is usually limited by slow hydrogen uptake and release. Nanoconfinementinfiltrating the metal hydride within a matrix of another material such as carbon — can, in certain instances, help make this process faster by shortening diffusion pathways for hydrogen or by changing the thermodynamic stability of the material.

However, the Livermore-Sandia team, in conjunction with collaborators from Mahidol University in Thailand and the National Institute of Standards and Technology, showed that nanoconfinement can have another, potentially more important consequence. They found that the presence of internal “nano-interfaces” within nanoconfined hydrides can alter which phases appear when the material is cycled.

The key is to get rid of the undesirable intermediate phases, which slow down the material’s performance as they are formed or consumed. If you can do that, then the storage capacity kinetics dramatically improve and the thermodynamic requirements to achieve full recharge become far more reasonable,” said Brandon Wood, an LLNL materials scientist and lead author of the paper. “In this material, the nano-interfaces do just that, as long as the nanoconfined particles are small enough. It’s really a new paradigm for hydrogen storage, since it means that the reactions can be changed by engineering internal microstructures.”

The research is reported  in the journal Advanced Materials Interfaces


Car Pollution: Nanoparticles Travel Directly From The Nose To The Brain

The closer a person lives to a source of pollution, like a traffic dense highway, the more likely they are to develop Alzheimer’s or dementia, according to a study by the University of Southern California (USC) that has linked a close connection to pollution and the diseases. In a mobile lab, located just off of one of Los Angeles’ busiest freeways, USC scientists used a state-of-the-art pollution particle collector capable of gathering nano-sized particulate matter.

car pollution


We have shown that, as you would expect, the closer you get to the sources of these particles in our case the freeways, the higher the concentrations. So there is an exponential decay with distance. That means basically that, the concentration of where we are right now and if we were, let’s just say 20 or 10 or 50 yards from the freeway, those levels would be probably 10 times higher than where we are right now,” says Costas Sioutas, USC Professor of Environmental Engineering.

That means proximity to high concentrations of fossil fuel pollution, like a congested freeway, could be hazardous. Particulate matter roughly 30 times thinner than the width of a human hair, called PM2.5, is inhaled and can travel directly through the nose into the brain. Once there, the particles cause inflammatory responses and can result in the buildup of a type of plaque, which is thought to further the progression of Alzheimer’s. “Our study brought in this new evidence and I would say probably so far the most convincing evidence that the particle may increase the risk of dementia. This is really a public health problem. And I think the policy makers need to be aware of that, the public health risk associated with high level of PM2.5,” explains Jiu-Chiuan Chen, Associate Professor of Preventive Medicine.

USC researchers analyzed the data of more than 3,500 women who had the APOE4 gene, the major known risk-factor gene for Alzheimer’s disease. It showed that, over the course of a decade, the women who lived in a location with high levels of the PM2.5 pollution were 92 percent more likely to develop dementia.


SpaceX Hyperloop A Step Closer To Reality

The Hyperloop high-speed transportation system has moved a step closer to reality. Teams competed to design subscale versions of the transport pods that could one day whisk passengers between San Francisco and Los Angeles in under half an hour. The competition was hosted by SpaceX and its founder, Elon Musk. Although Musk is not directly involved in the construction of the Hyperloop, the billionaire entrepreneur originally envisioned the concept, having created an open-source plan that encouraged others to build it. The idea is that passengers would travel through low-pressure steel tubes at up to 800 mph (1,288 kph), propelled by a magnetic accelerator. The fastest pod in the competition reached 58mph (93 kph). That was designed and built by a 35-person team from the Technical University of Munich, Germany.


What made our team stand out is actually a compressor which we bought out of an old aircraft. It’s there to reduce drag and give us some additional speed.” A team from Delft University of Technology in the Netherlands achieved the highest overall score in the competition for their pod with a levitation, stabilization and braking system based on permanent magnets“, said Josef Fleischmann, member of the WARR team from Technical University of Munich.

Hyperloop, the technology is pretty much there already, we just have to implement it. One of the things this competition is for is to show the world that we can do this and convince them that we should build it somewhere and get the ball rolling,” explains Mars Geuze, technical of Delft Hyperloop.
SpaceX has said it will hold a second competition, open to both new and existing student teams, in Summer 2017, this time focused only on maximum speed.


First Driverless Electric Bus Line Opened In Paris

Shuttling their way to a greener city. Paris opening its first driverless buses to the public on Monday. Fully electric and fully autonomous, the ‘EZ 10‘ transports up to 10 passengers across the Seine between two main stations. The buses use laser sensors to analyse their surroundings on the road and for now they don’t have to share it with any other vehicles.


“Fewer people come on board, its slower, its electric, it doesn’t pollute and it can be stored away more easily but it will never replace a traditional bus“, says Jose Gomes, who has been driving buses here for 26 years. He’ll oversee the smooth operation of the autonomous bus.

The shuttles come as Paris faces high pollution levels. City mayor Anna Hidalgo wants to reduce the number of cars, while authorities crack down on traffic restrictions. It may be a short 130m stretch for the buses but for Paris, it’s a big step towards promoting cleaner transport.


Electric Motorbike Round-The-World Trip

80-day round-the-world trips aren’t new – but using an electric motorbike built from scratch by students on them certainly is. Eindhoven University of Technology (Netherlands) riders drove up to 500 kilometres a day on their self-constructed Storm Wave bike, relying entirely on battery power. Other students rode behind in a bus, with one change of driver and battery swap per day.

Storm electric motorcycleCLICK ON THE IMAGE TO ENJOY THE VIDEO

With a full pack you can ride 400 kilometres on one single charge. But during our tour we had to drive more, so we had to re-energise quickly. So we just took the empty ones out, replaced them with charged ones, and we could ride again,” says Bas Verkaik, Spokeperson for Storm Eindhoven.  Key to the Storm Wave is its unique modular system of 24 individual batteries. This helped ease navigation of difficult roads in countries like Turkmenistan and Uzbekhistan.

When we faced those bad roads we just took, for example half of the batteries out, we have a lighter motorcycle, lower centre of gravity, which makes it easier to handle,” comments Bas Verkaik. Storm Wave also contains a gearbox, unusual for an electric motorcycle, but allowing greater acceleration and efficiency at high speeds.

The misconceptions people have about electric vehicles is that either they’re slow or they don’t have enough power or they can’t drive fast or far enough. With our motorcycle it can go from zero to 100 (kilometres per hour) in under five seconds, and probably could go even faster if we changed some specs… I think it looks pretty nice. That’s also a misconception that people have, that electric vehicles have to be futuristic and they don’t like the design, but I’ve only heard good things about this motorcycle” , explains Storm Wave driver Yorick Heidema.

The 23 students returned home in November after receiving huge interest in cities they drove through. They say they’ve showed the world that long-distance electric vehicle travel isn’t just feasible, but cool too.


Nanoparticles Trigger Dormant Viruses In Lung Cells

Nanoparticles from combustion engines can activate viruses that are dormant in lung tissue cells. This is the result of a study by researchers of Helmholtz Zentrum München, a partner in the German Center for Lung Research (DZL), which has now been published in the journal ‘Particle and Fibre Toxicology‘.

To evade the immune system, some viruses hide in cells of their host and persist there. In medical terminology, this state is referred to as a latent infection. If the immune system becomes weakened or if certain conditions change, the viruses become active again, begin to proliferate and destroy the host cell. A team of scientists led by Dr. Tobias Stöger of the Institute of Lung Biology and Prof. Dr. Heiko Adler, deputy head of the research unit Lung Repair and Regeneration at Helmholtz Zentrum München, now report that nanoparticles can also trigger this process.

car engine nanoparticles

From previous model studies we already knew that the inhalation of nanoparticles has an inflammatory effect and alters the immune system,” said study leader Stöger. Together with his colleagues Heiko Adler and Prof. Dr. Philippe Schmitt-Kopplin, he showed that “an exposure to nanoparticles can reactivate latent herpes viruses in the lung.


The Rise Of The Hydrogen Electric Car

Right now, if you want an alternative-fuel vehicle, you have to pick from offerings that either require gasoline or an electrical outlet. The gas-electric hybrid and the battery-powered car — your Toyota Priuses, Chevy Volts, and Teslas — are staples in this space. There are drawbacks for drivers of both types. You still have to buy gas for your hybrid and you have to plug in your Tesla — sometimes under less than favorable conditions — lest you be stranded someplace far away from a suitable plug. Beyond that, automakers have been out to find the next viable energy source. Plug-in vehicles are more or less proven to be the answer, but Toyota and a handful of other carmakers are investigating hydrogen.


That’s where the Toyota Mirai comes in. The Mirai‘s interior center stack has all the technology you would expect from a car that retails for $57,500, including navigation, Bluetooth, and USB connectivity. It’s all accessible by touch screens and robust digital displays.
A fill-up on hydrogen costs just about as much as regular gasoline in San Francisco. The Mirai gets an estimated 67 MPGe (67 Miles per gallon gasoline equivalent = 28,5 kilometers per liter)), according to Toyota.
It’s an ambitious project for Toyota because the fueling infrastructure for this car is minimal. There are only 33 public hydrogen-filling stations in the US, according to the US Department of Energy. Twenty-six of those stations are in California, and there’s one each in Connecticut, Massachusetts, and South Carolina.

If you include public and private hydrogen stations, then the total climbs to 58 — nationwide. Compare that to the more than 15,100 public electric-charging stations and the 168,000 retail gas stations in the US, and you can see the obvious drawback of hydrogen-powered cars. Despite this, the Mirai is an interesting project, and you must keep in mind that Japan at the Government level seems to bet on a massively hydrogen powered economy in the near future (fuel, heating, replacement of nuclear energy, trains, electric vehicles, etc…).


Japan Bets On Hydrogen As A Green Energy Source

Hydrogen gas is a promising alternative energy source to overcome our reliance on carbon-based fuels, and has the benefit of producing only water when it is reacted with oxygen. However, hydrogen is highly reactive and flammable, so it requires careful handling and storage. Typical hydrogen storage materials are limited by factors like water sensitivity, risk of explosion, difficulty of control of hydrogen-generation.

alstom-hydrogen-electric-train Hydrogen gas can be produced efficiently from organosilanes, some of which are suitably air-stable, non-toxic, and cheap. Catalysts that can efficiently produce hydrogen from organosilanes are therefore desired with the ultimate goal of realizing safe, inexpensive hydrogen production in high yield. Ideally, the catalyst should also operate at room temperature under aerobic conditions without the need for additional energy input. A research team led by Kiyotomi Kaneda and Takato Mitsudome at Osaka University have now developed a catalyst that realizes efficient environmentally friendly hydrogen production from organosilanes. The catalyst is composed of gold nanoparticles with a diameter of around 2 nm supported on hydroxyapatite.

The team then added the nanoparticle catalyst to solutions of different organosilanes to measure its ability to induce hydrogen production. The nanoparticle catalyst displayed the highest turnover frequency and number attained to date for hydrogen production catalysts from organosilanes. For example, the  converted 99% of dimethylphenylsilane to the corresponding silanol in just 9 min at room temperature, releasing an equimolar amount of hydrogen gas at the same time. Importantly, the catalyst was recyclable without loss of activity. On/off switching of hydrogen production was achieved using the nanoparticle catalyst because it could be easily separated from its organosilane substrate by filtration. The activity of the catalyst increased as the nanoparticle size decreased.

A prototype portable hydrogen fuel cell containing the nanoparticle catalyst and an organosilane substrate was fabricated. The fuel cell generated power in air at room temperature and could be switched on and off as desired.

Generation of hydrogen from inexpensive organosilane substrates under ambient conditions without additional energy input represents an exciting advance towards the goal of using hydrogen as a green energy source.


Diamond NanoThread, The New Wonder Material

Would you dress in diamond nanothreads? It’s not as far-fetched as you might think. And you’ll have a Brisbane-based carbon chemist and engineer to thank for it. QUT’s Dr Haifei Zhan is leading a global effort to work out how many ways humanity can use a newly-invented material with enormous potential – diamond nanothread (DNT). First created by Pennsylvania State University last year, one-dimensional DNT is similar to carbon nanotubes, hollow cylindrical tubes 10,000 times smaller than human hair, stronger than steel – but brittle.


DNT, by comparison, is even thinner, incorporating kinks of hydrogen in the carbon’s hollow structure, called Stone-Wale (SW) transformation defects, which I’ve discovered reduces brittleness and adds flexibility,” said Dr Zhan, from QUT’s School of Chemistry, Physics and Mechanical Engineering.

That structure makes DNT a great candidate for a range of uses. It’s possible DNT may become as ubiquitous a plastic in the future, used in everything from clothing to cars.

DNT does not look like a rock diamond. Rather, its name refers to the way the carbon atoms are packed together, similar to diamond, giving it its phenomenal strength. Dr Zhan has been modelling the properties of DNT since it was invented, using large-scale molecular dynamics simulations and high-performance computing. He was the first to realise the SW defects were the key to DNT’s versatility.

While both carbon nanotubes and DNT have great potential, the more I model DNT properties, the more it looks to be a superior material,” Dr Zhan said. “The SW defects give DNT a flexibility that rigid carbon nanotubes can’t replicate – think of it as the difference between sewing with uncooked spaghetti and cooked spaghetti. “My simulations have shown that the SW defects act like hinges, connecting straight sections of DNT. And by changing the spacing of those defects, we can a change – or tune – the flexibility of the DNT.

That research is published in the peer-reviewed publication Nanoscale.