Posts belonging to Category Automobile

Biodegradable Car

TU/Ecomotive (Netherlands) says ‘Lina‘ is the world’s first car with a fully biocomposite body structure. The 4-seat e-car‘s chassis uses a combination of bio-composite and bio-plastic made from sugarbeet.


It’s made of flax, the outside is made of flax fibres, together with polypropylene. It’s pressed and heated to make flat panels. In the middle you can see polylactic acid, the honeycomb structure of that material, which adds to the strength and weight savings of the sandwich panel. All structural parts of the car are made of this material,” says Yanic Van Riel, TU/Ecomotive.

The biocomposite has a similar strength-weight ratio to fibreglass, making the car light, greatly reducing battery size.

The car weighs only 310 kilograms which is really light for a car. That’s why we only need 30 kilograms of batteries. And on those 30 kilograms of battery packs we can drive around 100 kilometres, which is about four times more efficient than a BMW i3 right now and that’s in real city driving, so braking, stopping, accelerating, not just like the most optimal driving,” explains Yanic Van Riel.

Lina has a top speed of around 50 miles per hour. Electronic features include NFCnearfield communication technology.  “We can open our doors with NFC technology and a car will immediately recognise who is driving it. So if I’m opening it, it will save all the data from me and if someone else opens it, it will save his data. In that way we can use this car for carsharing apps, which other companies are creating. Also we have a hood system which projects the speed and all the information of the car into the front window, so we can see it through the window and still see the road, so it’s more safe,” adds Noud Van De Gevel, TU/Ecomotive.

The team hopes the prototype will soon be declared roadworthy, allowing it to be tested on Eindhoven city streets.


By 2025 Renewables Will Power 67 Percent Of South Australia

Declining renewables and energy storage costs will increasingly squeeze out gas-fired generation in South Australia as early as 2025, a joint research report conducted by Wood Mackenzie and GTM Research shows. The South Australia experience is noteworthy in a global power mix set to increasingly shift to renewable energy. South Australia retired its last coal plant in 2016 and is projected to have installed renewable energy capacity exceed its peak demand by 2020.

By 2025, wind, solar and battery costs will fall by 15 percent, 25 percent and 50 percent respectively. By then, renewables and batteries could offer a lower cost alternative to combined-cycle gas turbine plants, which are commonly used to manage base load power generation in South Australia. Meanwhile by 2035, renewables and batteries will provide a commercial solution for both base loads and peak loads. As a consequence, gas will increasingly be used just for emergency back-up.

One determining factor is the rate with which battery charging costs declines. By 2025, we expect battery charging cost to decrease as off-peak prices will gradually be set by excess wind generation. Battery storage then becomes a potential solution for managing peak loads,” said Bikal Pokharel, principal analyst for Wood Mackenzie‘s Asia-Pacific power and renewables .
By 2025 it’s expected that 67 percent of South Australia’s power capacity will come from renewables. Gas demand in the power sector will then decline by 70 percent.

Currently, South Australia’s peak loads are managed by open-cycle gas turbine (OCGT) plants. But by 2025, battery storage would be cheaper than OCGTs in managing peak loads even at gas price of A$7/mmbtu. OCGTs would then be relegated as emergency back-ups.”


Cheap, Robust Catalyst Splits Water Into Hydrogen And Oxygen

Splitting water into hydrogen and oxygen to produce clean energy can be simplified with a single catalyst developed by scientists at Rice University and the University of Houston. The electrolytic film produced at Rice and tested at Houston is a three-layer structure of nickel, graphene and a compound of iron, manganese and phosphorus. The foamy nickel gives the film a large surface, the conductive graphene protects the nickel from degrading and the metal phosphide carries out the reactionRice chemist Kenton Whitmire and Houston electrical and computer engineer Jiming Bao and their labs developed the film to overcome barriers that usually make a catalyst good for producing either oxygen or hydrogen, but not both simultaneously.

A catalyst developed by Rice University and the University of Houston splits water into hydrogen and oxygen without the need for expensive metals like platinum. This electron microscope image shows nickel foam coated with graphene and then the catalytic surface of iron, manganese and phosphorus

Regular metals sometimes oxidize during catalysis,” Whitmire said. “Normally, a hydrogen evolution reaction is done in acid and an oxygen evolution reaction is done in base. We have one material that is stable whether it’s in an acidic or basic solution.

The discovery builds upon the researchers’ creation of a simple oxygen-evolution catalyst revealed earlier this year. In that work, the team grew a catalyst directly on a semiconducting nanorod array that turned sunlight into energy for solar water splittingElectrocatalysis requires two catalysts, a cathode and an anode. When placed in water and charged, hydrogen will form at one electrode and oxygen at the other, and these gases are captured. But the process generally requires costly metals to operate as efficiently as the Rice team’s catalyst.

The standard for hydrogen evolution is platinum,” Whitmire explained. “We’re using Earth-abundant materials — iron, manganese and phosphorus — as opposed to noble metals that are much more expensive.

The robust material is the subject of a paper in Nano Energy.


Hydrogen-based Electric Bus

FAST, a student team from Eindhoven University of Technology (TU/e) in Netherlands, has designed the world’s first system that allows a bus to drive on formic acid. Their self-built system comprises an electric bus that is hooked up to a small trailer – which the students have christened ‘REX’ – in which formic acid is converted into electricity. The benefits of using formic acid are that it is sustainable, CO2-neutral, safe and liquid.


Hydrozine is the energy carrier’s official name. It’s 99% formic acid with a performance enhancing agent. What is striking is that Team FAST, consisting of 35 students, developed this so far unknown fuel all by itself. At the beginning of 2016 they presented an initial scale model that illustrated how it works. After another twenty months of hard work, they now have a system that is 42,000 times stronger and is capable of 25kW power.

In the trailer that was built by the team hydrozine is split into hydrogen and CO2. The hydrogen is then used to produce electricity that powers a city bus of the Eindhoven company VDL. The team calls the trailer a ‘range extender’, REX for short, because the trailer expands the existing range of the bus as a standalone component. The team is still running final tests with the aim of the bus actually operating by the end of this year.

The benefits of hydrozine are many. It is a cheap and safe alternative to the transport of hydrogen that normally requires large tanks and high pressure. The CO2 produced in splitting the hydrozine is also used in the production process, which results in zero net CO2. Hydrozine has four times as much energy density as a battery and since it is a liquid, very few modifications will be required to the current infrastructure of filling stations.


Sion, The Solar-Powered Car

What has room for 6 passengers, an all-electric range of up to 155 miles (250 kilometers), and a body covered in solar panels that can add as many as 18 miles (30 kilometers) of driving a day from sunlight? That would be the Sono Motors Sion, an innovative solar-powered car from a team of German entrepreneurs that is scheduled to have its world debut on July 27 (2017).

The Sion project was able to move forward thanks to an Indiegogo crowdfunding campaign last year that raised over a half million dollars. More than 1,000 people have participated so far.

The car will have two versions. The Urban comes with a 14.4 kilowatt-hour battery pack. It has a range of about 75 miles (121 kilometers) and will cost $13,200. The Extender version has a 30 kilowatt-hour battery and a range of 155 miles (250 kilometers). Its target price is $17,600. Neither price includes the battery. Like the Renault Zoe, customers will either buy the battery separately or lease it. The leasing option gives owners the flexibility to upgrade the battery later as improvements in battery technology become available.

The hood, roof, and rear hatch of the Sion are covered with monocrystalline silicon cells that are 21% efficient. On a sunny day, they can generate enough electricity to add 18 miles of range. The solar cells are 8 millimeters thick and embedded in a polycarbonate layer that is shatterproof, weather resistant, and light in weight. The Sion can also be 80% charged using an AC outlet in about 30 minutes, according to company claims. No DC charging option is available. The car also comes with an outlet that can power electronic devices.

Inside, all the seats of the 5 door hatchback fold flat, offering multiple configurations for carrying passengers and cargo. There is a 10 inch center display and smartphone connectivity via WiFi or Bluetooth. The ventilation system is called breSono and incorporates a dollop of moss, which is said to act as a natural filter when an electrical charge is applied.

The company will offer an online maintenance and repair system it calls reSono. It allows owners to order parts online and comes with a video that shows them how to install the parts when they arrive.  Or they can take the car and the parts to any local auto repair shop facility to get them installed.


Nano-based Material Is 60 Times More Efficient To Produce Hydrogen

Global climate change and the energy crisis mean that alternatives to fossil fuels are urgently needed. Among the cleanest low-carbon fuels is hydrogen, which can react with oxygen to release energy, emitting nothing more harmful than water (H2O) as the product. However, most hydrogen on earth is already locked into H2O (or other molecules), and cannot be used for power.

Hydrogen can be generated by splitting H2O, but this uses more energy than the produced hydrogen can give back. Water splitting is often driven by solar power, so-called “solar-to-hydrogenconversion. Materials like titanium oxide, known as semiconductors with the wide band-gap, are traditionally used to convert sunlight to chemical energy for the photocatalytic reaction. However, these materials are inefficient because only the ultraviolet (UV) part of light is absorbed—the rest spectrum of sunlight is wasted.

Now, a team in Osaka University has developed a material to harvest a broader spectrum of sunlight. The three-part composites of this material maximize both absorbing light and its efficiency for water splitting. The core is a traditional semiconductor, lanthanum titanium oxide (LTO). The LTO surface is partly coated with tiny specks of gold, known as nanoparticles. Finally, the gold-covered LTO is mixed with ultrathin sheets of the element black phosphorus (BP), which acts as a light absorber.

BP is a wonderful material for solar applications, because we can tune the frequency of light just by varying its thickness, from ultrathin to bulk,” the team leader Tetsuro Majima says. “This allows our new material to absorb visible and even near infrared light, which we could never achieve with LTO alone.”

By absorbing this broad sweep of energy, BP is stimulated to release electrons, which are then conducted to the gold nanoparticles coating the LTO. Gold nanoparticles also absorb visible light, causing some of its own electrons to be jolted out. The free electrons in both BP and gold nanoparticles are then transferred into the LTO semiconductor, where they act as an electric current for water splitting.

Hydrogen production using this material is enhanced not only by the broader spectrum of light absorption, but by the more efficient electron conduction, caused by the unique interface between two dimensional materials of BP and LTO. As a result, the material is 60 times more active than pure LTO.


Scalable Catalyst Produces Cheap Pure Hydrogen

The “clean-energy economy” always seems a few steps away but never quite here. Fossil fuels still power transportation, heating and cooling, and manufacturing, but a team of scientists from Penn State and Florida State University have come one step closer to inexpensive, clean hydrogen fuel with a lower cost and industrially scalable catalyst that produces pure hydrogen through a low-energy water-splitting process.

Hydrogen fuel cells can boost a clean-energy economy not only in the transportation sector, where fast fueling and vehicle range outpace battery-powered vehicles, but also to store electrical energy produced by solar and wind. This research is another step forward to reaching that goal.
Energy is the most important issue of our time, and for energy, fuel cells are crucially important, and then for fuel cells, hydrogen is most important,” said Yu Lei, Penn State doctoral student and first author of an ACS Nano paper describing the water-splitting catalyst she and her colleagues theoretically predicted and then synthesized in the lab. “People have been searching for a good catalyst that can efficiently split water into hydrogen and oxygen. During this process, there will be no side products that are not environmentally friendly.”

The current industrial method of producing hydrogen — steam reforming of methane — results in the release of carbon dioxide into the atmosphere. Other methods use waste heat, from sources such as advanced nuclear power plants or concentrated solar power, both of which face technical challenges for commercial feasibility. Another industrial process uses platinum as the catalyst to drive the water-splitting process. Although platinum is a near-perfect catalyst, it is also expensive. A cheaper catalyst could make hydrogen a reasonable alternative to fossil fuels in transportation, and power fuel cells for energy storage applications.

Molybdenum disulfide has been predicted as a possible replacement for platinum, because the Gibbs free energy for hydrogen absorption is close to zero,” said Mauricio Terrones, professor of physics, materials science and engineering, and chemistry, Penn State. The lower the Gibbs free energy, the less external energy has to be applied to produce a chemical reaction.


Self-Healing Lithium-Ion Batteries

Researchers at the University of Illinois have found a way to apply self-healing technology to lithium-ion batteries to make them more reliable and last longer.

The group developed a battery that uses a silicon nanoparticle composite material on the negatively charged side of the battery and a novel way to hold the composite together – a known problem with batteries that contain silicon.

Materials science and engineering professor Nancy Sottos and aerospace engineering professor Scott White led the study published in the journal Advanced Energy Materials.

“This work is particularly new to self-healing materials research because it is applied to materials that store energy,” White said. “It’s a different type of objective altogether. Instead of recovering structural performance, we’re healing the ability to store energy.”

The negatively charged electrode, or anode, inside the lithium-ion batteries that power our portable devices and electric cars are typically made of a graphite particle composite. These batteries work well, but it takes a long time for them to power up, and over time, the charge does not last as long as it did when the batteries were new.

Silicon has such a high capacity, and with that high capacity, you get more energy out of your battery, except it also undergoes a huge volume expansion as it cycles and self-pulverizes,” Sottos explained.

Past research found that battery anodes made from nanosized silicon particles are less likely to break down, but suffer from other problems.

You go through the charge-discharge cycle once, twice, three times, and eventually you lose capacity because the silicon particles start to break away from the binder,” White said.

To combat this problem, the group further refined the silicon anode by giving it the ability to fix itself on the fly. This self-healing happens through a reversible chemical bond at the interface between the silicon nanoparticles and polymer binder.


Bubbles And The Future Of Electric Cars

With about three times the energy capacity by weight of today’s lithium-ion batteries, lithium-air batteries could one day enable electric cars to drive farther on a single charge. But the technology has several holdups, including losing energy as it stores and releases its charge. If researchers could better understand the basic reactions that occur as the battery charges and discharges electricity, the battery’s performance could be improved. One reaction that hasn’t been fully explained is how oxygen blows bubbles inside a lithium-air battery when it discharges. The bubbles expand the battery and create wear and tear that can cause it to fail.

A paper in Nature Nanotechnology provides the first step-by-step explanation of how lithium-air batteries form bubbles. The research was aided by a first-of-a-kind video that shows bubbles inflating and later deflating inside a nanobattery. Researchers had previously only seen the bubbles, but not how they were created.

If we fully understand the bubble formation process, we could build better lithium-air batteries that create fewer bubbles,” noted the paper’s corresponding author, Chongmin Wang, of the Department of Energy’s Pacific Northwest National Laboratory (PNNL). “The result could be more compact and stable batteries that hold onto their charge longer.”

Wang works out of EMSL, the Environmental Molecular Sciences Laboratory, a DOE Office of Science user facility located at PNNL. His co-authors include other PNNL staff and a researcher from Tianjin Polytechnic University in China.

The team’s unique video may be a silent black-and-white film, but it provides plenty of action. Popping out from the battery’s flat surface is a grey bubble that grows bigger and bigger. Later, the bubble deflates, the top turning inside of itself until only a scrunched-up shell is left behind.

The popcorn-worthy flick was captured with an in-situ environmental transmission electron microscope at EMSL. Wang and his colleagues built their tiny battery inside the microscope’s column. This enabled them to watch as the battery charged and discharged inside.

Video evidence led the team to propose that as the battery discharges, a sphere of lithium superoxide jets out from the battery’s positive electrode and becomes coated with lithium oxide. The sphere’s superoxide interior then goes through a chemical reaction that forms lithium peroxide and oxygen. Oxygen gas is released and inflates the bubble. When the battery charges, lithium peroxide decomposes, and leaves the former bubble to look like a deflated balloon.



Clean Hydrogen Produced From Biomass

A team of scientists at the University of Cambridge has developed a way of using solar power to generate a fuel that is both sustainable and relatively cheap to produce. It’s using natural light to generate hydrogen from biomass. One of the challenges facing modern society is what it does with its waste products. As natural resources decline in abundance, using waste for energy is becoming more pressing for both governments and business. Biomass has been a source of heat and energy since the beginning of recorded history.  The planet’s oil reserves are derived from ancient biomass which has been subjected to high pressures and temperatures over millions of years. Lignocellulose is the main component of plant biomass and up to now its conversion into hydrogen has only been achieved through a gasification process which uses high temperatures to decompose it fully.

biomass can produce hydrogen

Lignocellulose is nature’s equivalent to armoured concrete. It consists of strong, highly crystalline cellulose fibres, that are interwoven with lignin and hemicellulose which act as a glue. This rigid structure has evolved to give plants and trees mechanical stability and protect them from degradation, and makes chemical utilisation of lignocellulose so challenging,” says  Dr Moritz Kuehnel, from the Department of Chemistry at the University of Cambridge and co-author of the research.

The new technology relies on a simple photocatalytic conversion process. Catalytic nanoparticles are added to alkaline water in which the biomass is suspended. This is then placed in front of a light in the lab which mimics solar light. The solution is ideal for absorbing this light and converting the biomass into gaseous hydrogen which can then be collected from the headspace. The hydrogen is free of fuel-cell inhibitors, such as carbon monoxide, which allows it to be used for power.

The findings have been  published in Nature Energy.


NanoCar Race

The NanoCar Race is an event in which molecular machines compete on a nano-sized racetrack. These “NanoCars” or molecule-cars can have real wheels, an actual chassis…and are propelled by the energy of electric pulses! Nothing is visible to the naked eye, however a unique microscope located in Toulouse (France) will make it possible to follow the race. A genuine scientific prowess and international human adventure, the race is a one-off event, and will be broadcast live on the web, as well as at the Quai des Savoirs, science center in Toulouse.


The NanoCar race takes place on a very small scale, that of molecules and atoms: the nano scale…as in nanometer! A nanometer is a billionth of a meter, or 0.000000001 meters or 10 -9 m. In short, it is 500,000 times thinner then a line drawn by a ball point pen; 30,000 times thinner than the width of a hair; 100 times smaller than a DNA molecule; 4 atoms of silicon lined up next to one another.

A very powerful microscope is necessary to observe molecules and atoms: the scanning tunneling microscope (STM) makes this possible, and it is also responsible for propelling the NanoCars. The scanning tunneling microscope was invented in 1981 by Gerd Binnig and Heinrich Rohrer, and earned them the Nobel Prize in Physics in 1986. The tunnel effect is a phenomenon in quantum mechanics: using a tip and an electric current, the microscope will use this phenomenon to determine the electric conductance between the tip and the surface, in other words the amount of current that is passing through.

nanocar in movement Screening provides an electronic map of the surface and of each atom or molecule placed on it.At the CNRS‘s Centre d’élaboration de matériaux et d’études structurales (CEMES) in Toulouse, it is the one of a kind STM microscope that makes the race possible: the equivalent of four scanning tunneling microscopes, this device is the only one able to simultaneously and independently map four sections of the track in real time, thanks to its four tungsten tips.


Clean Renewable Source Of Hydrogen Fuel For Electric Car

Rice University scientists have created an efficient, simple-to-manufacture oxygen-evolution catalyst that pairs well with semiconductors for solar water splitting, the conversion of solar energy to chemical energy in the form of hydrogen and oxygen.

anode RiceA photo shows an array of titanium dioxide nanorods with an even coating of an iron, manganese and phosphorus catalyst. The combination developed by scientists at Rice University and the University of Houston is a highly efficient photoanode for artificial photosynthesis. Click on the image for a larger version

The lab of Kenton Whitmire, a Rice professor of chemistry, teamed up with researchers at the University of Houston and discovered that growing a layer of an active catalyst directly on the surface of a light-absorbing nanorod array produced an artificial photosynthesis material that could split water at the full theoretical potential of the light-absorbing semiconductor with sunlight. An oxygen-evolution  catalyst splits water into hydrogen and oxygen. Finding a clean renewable source of hydrogen fuel is the focus of extensive research, but the technology has not yet been commercialized.

The Rice team came up with a way to combine three of the most abundant metalsiron, manganese and phosphorus — into a precursor that can be deposited directly onto any substrate without damaging it. To demonstrate the material, the lab placed the precursor into its custom chemical vapor deposition (CVD) furnace and used it to coat an array of light-absorbing, semiconducting titanium dioxide nanorods. The combined material, called a photoanode, showed excellent stability while reaching a current density of 10 milliamps per square centimeter, the researchers reported.

The results appear in two new studies. The first, on the creation of the films, appears in Chemistry: A European Journal. The second, which details the creation of photoanodes, appears in ACS Nano.