Bubbles And The Future Of Electric Cars

With about three times the energy capacity by weight of today’s lithium-ion batteries, lithium-air batteries could one day enable electric cars to drive farther on a single charge. But the technology has several holdups, including losing energy as it stores and releases its charge. If researchers could better understand the basic reactions that occur as the battery charges and discharges electricity, the battery’s performance could be improved. One reaction that hasn’t been fully explained is how oxygen blows bubbles inside a lithium-air battery when it discharges. The bubbles expand the battery and create wear and tear that can cause it to fail.

A paper in Nature Nanotechnology provides the first step-by-step explanation of how lithium-air batteries form bubbles. The research was aided by a first-of-a-kind video that shows bubbles inflating and later deflating inside a nanobattery. Researchers had previously only seen the bubbles, but not how they were created.

If we fully understand the bubble formation process, we could build better lithium-air batteries that create fewer bubbles,” noted the paper’s corresponding author, Chongmin Wang, of the Department of Energy’s Pacific Northwest National Laboratory (PNNL). “The result could be more compact and stable batteries that hold onto their charge longer.”

Wang works out of EMSL, the Environmental Molecular Sciences Laboratory, a DOE Office of Science user facility located at PNNL. His co-authors include other PNNL staff and a researcher from Tianjin Polytechnic University in China.

The team’s unique video may be a silent black-and-white film, but it provides plenty of action. Popping out from the battery’s flat surface is a grey bubble that grows bigger and bigger. Later, the bubble deflates, the top turning inside of itself until only a scrunched-up shell is left behind.

The popcorn-worthy flick was captured with an in-situ environmental transmission electron microscope at EMSL. Wang and his colleagues built their tiny battery inside the microscope’s column. This enabled them to watch as the battery charged and discharged inside.

Video evidence led the team to propose that as the battery discharges, a sphere of lithium superoxide jets out from the battery’s positive electrode and becomes coated with lithium oxide. The sphere’s superoxide interior then goes through a chemical reaction that forms lithium peroxide and oxygen. Oxygen gas is released and inflates the bubble. When the battery charges, lithium peroxide decomposes, and leaves the former bubble to look like a deflated balloon.

Source: http://www.pnnl.gov/


First Driverless Electric Bus Line Opened In Paris

Shuttling their way to a greener city. Paris opening its first driverless buses to the public on Monday. Fully electric and fully autonomous, the ‘EZ 10‘ transports up to 10 passengers across the Seine between two main stations. The buses use laser sensors to analyse their surroundings on the road and for now they don’t have to share it with any other vehicles.


“Fewer people come on board, its slower, its electric, it doesn’t pollute and it can be stored away more easily but it will never replace a traditional bus“, says Jose Gomes, who has been driving buses here for 26 years. He’ll oversee the smooth operation of the autonomous bus.

The shuttles come as Paris faces high pollution levels. City mayor Anna Hidalgo wants to reduce the number of cars, while authorities crack down on traffic restrictions. It may be a short 130m stretch for the buses but for Paris, it’s a big step towards promoting cleaner transport.

Source: http://www.reuters.com/

The Rise Of The Hydrogen Electric Car

Right now, if you want an alternative-fuel vehicle, you have to pick from offerings that either require gasoline or an electrical outlet. The gas-electric hybrid and the battery-powered car — your Toyota Priuses, Chevy Volts, and Teslas — are staples in this space. There are drawbacks for drivers of both types. You still have to buy gas for your hybrid and you have to plug in your Tesla — sometimes under less than favorable conditions — lest you be stranded someplace far away from a suitable plug. Beyond that, automakers have been out to find the next viable energy source. Plug-in vehicles are more or less proven to be the answer, but Toyota and a handful of other carmakers are investigating hydrogen.


That’s where the Toyota Mirai comes in. The Mirai‘s interior center stack has all the technology you would expect from a car that retails for $57,500, including navigation, Bluetooth, and USB connectivity. It’s all accessible by touch screens and robust digital displays.
A fill-up on hydrogen costs just about as much as regular gasoline in San Francisco. The Mirai gets an estimated 67 MPGe (67 Miles per gallon gasoline equivalent = 28,5 kilometers per liter)), according to Toyota.
It’s an ambitious project for Toyota because the fueling infrastructure for this car is minimal. There are only 33 public hydrogen-filling stations in the US, according to the US Department of Energy. Twenty-six of those stations are in California, and there’s one each in Connecticut, Massachusetts, and South Carolina.

If you include public and private hydrogen stations, then the total climbs to 58 — nationwide. Compare that to the more than 15,100 public electric-charging stations and the 168,000 retail gas stations in the US, and you can see the obvious drawback of hydrogen-powered cars. Despite this, the Mirai is an interesting project, and you must keep in mind that Japan at the Government level seems to bet on a massively hydrogen powered economy in the near future (fuel, heating, replacement of nuclear energy, trains, electric vehicles, etc…).

Source: http://www.businessinsider.com

Electric Car: Graphene Is The Next Revolution

Henrik Fisker, the famed automotive designer known for his work on iconic vehicles such as the Aston Martin DB9, the Aston Martin V8 Vantage and the BMW Z8, did not do well in an electric car venture that he launched in 2007. Fisker Automotive was a rival to Tesla Motors in the early days of the electric car industry, but it was not able to deliver its promised vehicles and had to declare bankruptcy in 2013. However, it seems that Fisker has not pushed electric cars out of his mind, as it was recently reported that he is returning to the electric vehicle scene with a new company named Fisker Inc. that will be taking form next year.

With rival Tesla Motors now the perceived leader in the industry, Fisker Inc. is looking to make a splash. It seems that the new company would be able to do so, as Fisker revealed that instead of the traditional lithium-ion batteries, Fisker Inc. vehicles will be powered by a new kind of battery known as graphene supercapacitors.


It was earlier reported that the luxury electric car that Fisker Inc. is working on will have a full-charge range that will reach over 400 miles, which is significant because the longest range that Tesla Motors offers through its vehicles is 315 miles on the high-end version of the Model S. The 400-mile range is said to be made possible by the usage of graphene in electric car batteries, with the technology being referred to by Fisker as the “next big step” in the industry.

According to Michigan Technological University assistant professor Lucia Gauchia, graphene has a higher electron mobility and presents a higher active surface, which are characteristics that lead to faster charging times and expanded energy storage, respectively, when used for batteries.

Graphene, however, has so far been associated with high production costs. Fisker is looking to solve that problem and mass produce graphene through a machine that his battery division, named Fisker Nanotech, is looking to have patented. Through the machine, 1,000 kilograms of graphene can be produced at a cost of just 10 cents per gram.

Our battery technology is so much better than anything out there,” Fisker said, amid the many improvements that his company has made on the material’s application to electric car batteries.

Fisker also said that the first Fisker Inc. electric car is being planned to be unveiled in the second half of next year. The luxury electric vehicle will only have limited production, and will be in the price range of the higher-end models of the Model S. However, Fisker said that he will then be producing consumer-friendly electric vehicles that will be even cheaper compared with the Tesla Model 3 and the Chevrolet Bolt, following the footsteps of its rival.

Source: http://www.techtimes.com/

Electric Car: Nanofiber Electrodes Boost Fuel Cells By 30 Percent

At the same time Honda and Toyota are introducing fuel cell cars to the U.S. market, a team of researchers from Vanderbilt University, Nissan North America and Georgia Institute of Technology have teamed up to create a new technology designed to give fuel cells more oomph. The project is part of a $13 million Department of Energy program to advance fuel cell performance and durability and hydrogen storage technologies announced last month.

hydrogen fuel cells

Fuel cells were invented back in 1839 but their first real world application wasn’t until the 1960’s when NASA used them to power the Apollo spacecraft. Fuel cells need fuel and air to run, like a gasoline engine, but they produce electricity, like a battery. In hydrogen/air fuel cells, hydrogen flows into one side of the device. Air is pumped into the other side. At the anode, the hydrogen is oxidized into protons. The protons flow to the cathode where the air is channeled, reducing the oxygen to form water. Special catalysts in the anode and cathode allow these reactions to occur spontaneously, producing electricity in the process. Fuel cells convert fuel to electricity with efficiencies ranging from 40 percent to 60 percent. They have no moving parts so they are very quiet. With the only waste product being water, they are environmentally friendly.The $2.5 million collaboration is based on a new nanofiber mat technology developed by Peter Pintauro, Professor of Chemical Engineering at Vanderbilt, that replaces the conventional electrodes used in fuel cells. The nanofiber electrodes boost the power output of fuel cells by 30 percent while being less expensive and more durable than conventional catalyst layers. The technology has been patented by Vanderbilt and licensed to Merck KGaA in Germany, which is working with major auto manufacturers in applying it to the next generation of automotive fuel cells.

Conventional fuel cells use thin sheets of catalyst particles mixed with a polymer binder for the electrodes. The catalyst is typically platinum on carbon powder. The Vanderbilt approach replaces these solid sheets with mats made from a tangle of polymer fibers that are each a fraction of the thickness of a human hair made by a process called electrospinning. Particles of catalyst are bonded to the fibers. The very small diameter of the fibers means that there is a larger surface area of catalyst available for hydrogen and oxygen gas reactions during fuel cell operation. The pores between fibers in the mat electrode also facilitate the removal of the waste water. The unique fiber electrode structure results in higher fuel cell power, with less expensive platinum.
Source: http://news.vanderbilt.edu/

How To Increase By Six Times The Capacity Of Lithium-Ion Batteries

The capacity of lithium-ion batteries might be increased by six times by using anodes made of silicon instead of graphite. A team from the Helmholtz-Zentrum Berlin (HZB) Institute of Soft Matter and Functional Materials has observed for the first time in detail how lithium ions migrate into thin films of silicon. It was shown that extremely thin layers of silicon would be sufficient to achieve the maximal load of lithium.

The team was able to show through neutron measurements made at the Institut Laue-Langevin in Grenoble, France, that lithium ions do not penetrate deeply into the silicon. During the charge cycle, a 20-nm anode layer develops containing an extremely high proportion of lithium. This means extremely thin layers of silicon would be sufficient to achieve the maximal load of lithium.
lithium-ion battery

Lithium-ion batteries provide laptops, smart phones, and tablet computers with reliable energy. However, electric vehicles have not gotten as far along with conventional lithium-ion batteries. This is due to currently utilised electrode materials such as graphite only being able to stably adsorb a limited number of lithium ions, restricting the capacity of these batteries. Semiconductor materials like silicon are therefore receiving attention as alternative electrodes for lithium batteries. Bulk silicon is able to absorb enormous quantities of lithium. However, the migration of the lithium ions destroys the crystal structure of silicon. This can swell the volume by a factor of three, which leads to major mechanical stresses. Now a team from the HZB Institute for Soft Matter and Functional Materials headed by Prof. Matthias Ballauff has directly observed for the first time a lithium-silicon half-cell during its charging and discharge cycles. “We were able to precisely track where the lithium ions adsorb in the silicon electrode using neutron reflectometry methods, and also how fast they were moving”, comments Dr. Beatrix-Kamelia Seidlhofer, who carried out the experiments using the neutron source located at the Institute Laue-Langevin.

She discovered two different zones during her investigations. Near the boundary to the electrolytes, a roughly 20-nm layer formed having extremely high lithium content: 25 lithium atoms were lodged among 10 silicon atoms. A second adjacent layer contained only one lithium atom for ten silicon atoms. Both layers together are less than 100 nm thick after the second charging cycle.

After discharge, about one lithium ion per silicon node in the electrode remained in the silicon boundary layer exposed to the electrolytes. Seidlhofer calculates from this that the theoretical maximum capacity of these types of silicon-lithium batteries lies at about 2300 mAh/g. This is more than six times the theoretical maximum attainable capacity for a lithium-ion battery constructed with graphite (372 mAh/g).

The results ar published in the journal ACSnano (DOI: 10.1021/acsnano.6b02032).

Source: https://www.helmholtz-berlin.de/

Engineered Nanoparticles Replace Rare-earth Materials

Technologies from wind turbines to electric vehicles rely on critical materials called rare-earth elements. These elements, though often abundant, can be difficult and increasingly costly to come by. Now, scientists from the Laboratory of Molecular Magnetism (LAMM) of the University of Florence in Italy,  looking for alternatives have reported in ACS’ journal Chemistry of Materials a new way to make nanoparticles that could replace some rare-earth materials and help ensure the continued supply of products people have come to depend on.

rare-earth element

Rare-earth elements have unique characteristics that make them very useful. For example, the world’s strongest magnets are made with neodymium. A little too powerful for your refrigerator, these magnets are incorporated into computer disk drives, or nanocoputers, power windows and wind turbines. But rare earths are challenging to mine and process, and prices can rise quickly in a short period of time. Given the increasing demand for rare earths, Alberto López-Ortega, Claudio Sangregorio and colleagues (LAMM) set out to find substitutes for use in strong magnets.

The researchers used a mixed iron-cobalt oleate complex in a one-step synthetic approach to produce magnetic core-shell nanoparticles. The resulting materials showed strong magnetic properties and energy-storing capabilities. Their approach could signal an efficient new strategy toward replacing rare earths in permanent magnets and keeping costs stable, the researchers say.

Source: http://www.eurekalert.org/

Electric Car: New Hydrogen Filling Station

A new hydrogen filling station is open to the public in London It creates the gas on site from tap water and renewable energy — a first for the British capital. The station uses electricity generated from renewable sources such as wind power to split water into hydrogen and oxygen. The whole facility can also be switched on and off by the power company to help them balance demand on the grid. Green power company ITM says it helps the problem of what to do with the UK’s excess renewable energy.


You can re-fuel it in 3 minutes and it will go over three hundred miles (483 km). They are the limitations of a plug-in electric vehicle. You also export the energy from the power grid in a much more effective way,” says Dr Graham Cooley,  ITM Chief Executive.

Refuelling at the site fills the tank with 5kg of pressurised hydrogen which costs around of £10 per kilogram (12,7 euros or 14,5 Dollars), giving a range of around 300 miles. Three different models of hydrogen-powered cars are available in the UK at present, including the Hyundai ix35, though only a handful of people actually drive them.

The issue is dispensing it and delivering it to vehicles which is what we see here today in terms of the new infrastructure being developed. It’s the delivery of the fuel and it’s a relatively straightforward process to do it,”  comments Jon Hunt from the company Toyota.

The technology is still nascent — and, like the cars, hydrogen filling stations remain relatively scarce across Europe. But there are set to be 12 open across the UK by the end of next year.

Source:  https://en.wikipedia.org/

Hydrogen Electric Car Powered By Fuel Cells 4 Times More Efficient

Inspired by the humble cactus, a new type of membrane has the potential to significantly boost the performance of fuel cells and transform the electric vehicle industry. The membrane, developed by scientists from CSIRO (Australia) and Hanyang University in Korea, was described today in the journal Nature . The paper shows that in hot conditions the membrane, which features a water repellent skin, can improve the efficiency of fuel cells by a factor of four.

According to CSIRO researcher and co-author Dr Aaron Thornton, the skin works in a similar way to a cactus plant, which thrives by retaining water in harsh and arid environments.


Fuel cells, like the ones used in electric vehicles, generate energy by mixing together simple gases, like hydrogen and oxygen. However, in order to maintain performance, proton exchange membrane fuel cells – or PEMFCs – need to stay constantly hydrated,” Dr Thornton said.

At the moment this is achieved by placing the cells alongside a radiator, water reservoir and a humidifier. The downside is that when used in a vehicle, these occupy a large amount of space and consume significant power,” he added.

According to CSIRO researcher and co-author Dr Cara Doherty, the team’s new cactus-inspired solution offers an alternative. A cactus plant has tiny cracks, called stomatal pores, which open at night when it is cool and humid, and close during the day when the conditions are hot and arid. This helps it retain water,” Dr Doherty said. “This membrane works in a similar way. Water is generated by an electrochemical reaction, which is then regulated through nano-cracks within the skin. The cracks widen when exposed to humidifying conditions, and close up when it is drier. This means that fuel cells can remain hydrated without the need for bulky external humidifier equipment. We also found that the skin made the fuel cells up to four times as efficient in hot and dry conditions,” she added.

Professor Young Moo Lee from Hanyang University, who led the research, said that this could have major implications for many industries, including the development of electric vehicles.

Source: http://www.csiro.au/

Nanotechnology Improves Next Generation Of Batteries

In the global race to create more efficient and long-lasting batteries, some are betting on nanotechnology — the use of minuscule parts — as the most likely to yield a breakthrough. Improving batteries’ performance is key to the development and success of many much-hyped technologies, from solar and wind energy to electric cars. They need to hold more energy, last longer, be cheaper and safer. Research into how to achieve that has followed several avenues, from using different materials than the existing lithium-ion batteries to changing the internal structure of batteries using nanoparticles — parts so small they are invisible to the naked eye. Nanotechnology can increase the size and surface of batteries electrodes, the rods inside the batteries that absorb the energy. It does so by effectively making the electrodes sponge-like, so that they can absorb more energy during charging and ultimately increasing the energy storage capacity. Prague-based company HE3DA in Czech Republic has developed such a technology by using the nanotechnology to move from the current flat electrodes to make them three dimensional. With prototypes undergoing successful testing, it hopes to have the battery on the market at the end of this year.

Tesla Model 3

In the future, this will be the mainstream,” said Jan Prochazka, the president. He said it would be targeted at high-intensity industries like automobiles and the energy sector, rather than mobile phones, because that is where it can make the biggest difference through its use of his bigger electrodes.

In combination with an internal cooling system the batteries, which are being tested now, should be safe from overheating or exploding, a major concern with existing technologies. Researchers at the University of Michigan and MIT have likewise focused on nanotechnology to improve the existing lithium-ion technology. Others have sought to use different materials. One of the most promising is lithium oxygen, which theoretically could store five to 10 times the energy of a lithium ion battery, but there have been a number of technical problems that made it inefficient. Batteries based on sodium-ion, aluminium-air and aluminium-graphite are also being explored. There’s even research on a battery powered by urine.

Source: http://www.he3da.cz/

China: A Cheap And Frugal Electric Car

Renault-Nissan will develop an affordable electric car for China because the alliance’s current offering, the Nissan Leaf, is too expensive for the local market. Nissan sold just 1,273 units of the Venucia e30, a local version of the Leaf, in China last year, according to the China Association of Automobile Manufacturers (CAAM). The car starts at 242,800 yuan ($36,900).

Venucia-Viwa-500x283I am unhappy with Venucia sales. We envisaged much more than that. We know price is a handicap,” said Carlos Ghosn, Chief Excecutive Officer of Renault-Nissan. “For me the solution will be a very cheap electric car,” Ghosn told journalists at the opening of Renault’s plant here in central China.. Ghosn did not comment on possible sales in markets outside China such as Europe or the size of the car.

China’s market for cars termed ‘new energy vehicles‘ — pure EVs and plug-in hybrids — has rapidly expanded in the last few years to reach 379,000 in 2015, according to government figures quoted by the China Daily newspaper. Ghosn said that despite the incentives, most sales were very cheap electric vehicles made by local brands costing between 30,00050,000 yuan ($4,600$7,000). The biggest selling electric car last year was the tiny Kandi EV city car with 16,736 sold, according to CAAM.

The government is saying we want more electric cars. The public is saying ‘yes, but we want them cheap‘, Ghosn said. He added Renault-Nissan would start development of an affordable electric car but the automakers first had to define what the public would accept. “We need to work out what are the best compromises between acceptable performance and lowest price possible“.

Source: http://europe.autonews.com/

Electric Car: Will the Next Tesla Sell for $25,000?

Tesla Motors Inc. was built with one overriding objective: to bring electric cars to the masses. After more than a decade of work, Tesla Chief Executive Officer Elon Musk believes it’s just about time. The company is set to begin taking pre-orders on its$35,000 Model 3 next month—and by $35,000, Tesla really means as little as $25,000Tesla has confirmed that the $35,000 price tag on the Model 3 doesn’t include the significant federal and state incentives available to electric car buyers. Official confirmation from the company echoes what Musk told reporters at an auto show more than a year ago: “When I say $35,000, I’m talking about without any credits.

The distinction Tesla is making here between the price before and after tax subsidies is crucial; these tax incentives can knock off as much as $10,000 from the cost of purchase, drastically increasing the size of the market for the Model 3. The pre-subsidy price was increasingly in doubt after the company set the starting price of its Model X luxury SUV at $80,000, more than analysts initially expected1.

Tesla Model 3
We can confirm it’s $35,000 before incentives,” a Tesla spokeswoman, Khobi Brooklyn, told Bloomberg.
We haven’t changed our minds.

To understand why pricing is so important, just look at what Americans are currently willing to spend. The average new car costs about $31,000, according to an analysis by Salim Morsy of Bloomberg New Energy Finance. Almost all the mass-market vehicles sold above that price threshold are SUVs and trucks. There’s only one car comparable in size to the Model 3 that amasses more than 100,000 in annual sales with a $35,000 price tag: the BMW 3 Series.

Another crucial figure: the range. Tesla announces 250 miles. At 25,000 dollars, the Tesla Model 3 is definitively competitive.

Source: http://www.bloomberg.com/